H.E. Jose R. Romero Ambassador Extraordinary and Plenipotentiary 1949 – 1953
H.E. Leon Maria Guerrero Ambassador Extraordinary and Plenipotentiary 1954 – 1961
H.E. Melquiades J. Gamboa Ambassador Extraordinary and Plenipotentiary 1962 – 1963
H.E. Marcial P. Lichauco Ambassador Extraordinary and Plenipotentiary 1963 – 1966
H.E Narciso G. Reyes Ambassador Extraordinary and Plenipotentiary 1966 – 1970
H.E. Jaime Zobel de Ayala Ambassador Extraordinary and Plenipotentiary 1970 – 1975
H.E. Jose Manuel Stilianopoulos Ambassador Extraordinary and Plenipotentiary 1977 – 1982
H.E Jose Vicente Cruz Ambassador Extraordinary and Plenipotentiary 1982 – 1985
H.E. Juan T. Quimson Ambassador Extraordinary and Plenipotentiary 1986 – 1988
H.E. Tomas T. Syquia Ambassador Extraordinary and Plenipotentiary 1989 – 1990
H.E. Manuel T. Yan Ambassador Extraordinary and Plenipotentiary 1991 – 1992
H.E. Jesus P. Tambunting Ambassador Extraordinary and Plenipotentiary 1993 – 1998
Hon. Maria Rowena Mendoza Sánchez Chargé d’Affaires, ad interim 1998
H.E. Cesar B. Bautista Ambassador Extraordinary and Plenipotentiary 1999 – 2003
H.E. Edgardo B. Espiritu Ambassador Extraordinary and Plenipotentiary 2003 – 2009
H.E. Antonio M. Lagdameo Ambassador Extraordinary and Plenipotentiary 2009 – 2010
Hon. Reynaldo A. Catapang Chargé d’Affaires, ad interim 2010 – 2011